Download Atomic and Molecular Manipulation, Volume 2 by Andrew J. Mayne, Gérald Dujardin PDF

By Andrew J. Mayne, Gérald Dujardin

ISBN-10: 0080963552

ISBN-13: 9780080963556

Work with person atoms and molecules goals to illustrate that miniaturized digital, optical, magnetic, and mechanical units can function eventually even on the point of a unmarried atom or molecule. As such, atomic and molecular manipulation has performed an emblematic position within the improvement of the sector of nanoscience. New tools in line with using the scanning tunnelling microscope (STM) were constructed to signify and manage the entire levels of freedom of person atoms and molecules with an exceptional precision. meanwhile, new thoughts have emerged to layout molecules and substrates having particular optical, mechanical and digital services, therefore starting how one can the fabrication of actual nano-machines. Manipulation of person atoms and molecules has additionally spread out thoroughly new parts of analysis and information, elevating basic questions of "Optics on the atomic scale", "Mechanics on the atomic scale", Electronics on the atomic scale", "Quantum physics on the atomic scale", and "Chemistry on the atomic scale". This booklet goals to demonstrate the most points of this ongoing clinical event and to expect the most important demanding situations for the longer term in "Atomic and molecular manipulation" from primary wisdom to the fabrication of atomic-scale devices.

  • Provides a extensive evaluation of the sector to assist these new and stepping into this study area
  • Presents a overview of the old improvement and evolution of the field
  • Offers a transparent custom-made view of present scanning probe microscopy learn from international experts

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Additional resources for Atomic and Molecular Manipulation, Volume 2

Example text

Therefore, the LUMO image allows an easy determination of the position of the imino hydrogens: the arms with the hydrogens exhibit a single lobe structure at the end, whereas along the other two arms, there is a nodal plane. Most interestingly, the molecules can be switched in a controlled fashion between the two possible hydrogen positions using inelastic tunnelling. The hydrogen tautomerization can be induced by positioning the tip somewhere above the molecule and increasing the bias to a value significantly above the LUMO resonance.

4. 15 The switch consists of a free-base naphthalocyanine molecule, which hosts two hydrogen atoms in its central cavity. The hydrogens reduce the otherwise fourfold rotational symmetry (D4h) of the molecule to a twofold symmetry (D2h). Therefore, there are two equivalent positions of the two hydrogens. As in the case of pentacene, the frontier molecular orbitals can be directly imaged. 18. The molecule is adsorbed along the nonpolar direction of the underlying NaCl bilayer film on Cu(111). As in the case of pentacene, the images acquired at voltages corresponding to molecular resonances compare very well with the calculated contours of constant density of the electronic wave functions (DFT; Ref.

In the case of an insulating substrate, the ratio of diffusion barrier to binding energy is much larger so that excitation by IET is already required to induce the lateral movement. 6,10,12 The actual bond formation between the metal atom and the molecule, however, requires a smaller activation energy, such that the IET excitation process applied to achieve lateral movement is already sufficient to also initiate the synthesis. 16 shows the bond formation between a pentacene molecule and a gold atom on a bilayer of NaCl.

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Atomic and Molecular Manipulation, Volume 2 by Andrew J. Mayne, Gérald Dujardin

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